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Intelligent Polymers for Opto-Electronic ApplicationsDepartment of Chemistry, Sophia University, 7-1 Kioi-Cho, Chiyoda-Ku, Tokyo 102, Japan
Thin films of poly(benzothiazole) containing thiophene in main chains were success fully prepared at air/water interface by using Langmuir-Blodgett (LB) method and they were transferred onto quartz plate as multi-layers built-up films. Third harmonic generation of the thin film was measured as New ion conductive polymer complexes were formed by dissolving poly(1-butyl-4-vinylpyri dinium) salts into room temperature molten salts consisting of 1-butylpyridinium salts and aluminium chloride. The viscoelastic films were fabricated from the molten salts added at least 10 mol % of the polypyridinium salts. The ionic conductivities of the polymer complexes were in the range of 10-3-10-4 Scm-1 at room temperature and were affected by their composition.
Journal of Intelligent Material Systems and Structures, Vol. 5, No. 5,
619-625 (1994) |
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3 = 10-11 esu which was 10 times higher than that of normal poly(ben zothiazole) without having thiophene.