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Journal of Intelligent Material Systems and Structures
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A Sensor for Measuring Gel Phase-Transition Temperature, with Potential as a Metal Ion Detector

Deron K. Jackson

Steven B. Leeb

Ahmed Mitwalli

Dahlene Fusco

Laboratory for Electromagnetic and Electronic Systems, Massachusetts Institute of Technology, Cambridge, MA 02139

Changnan Wang

Toyoichi Tanaka

Center for Material Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139

This paper describes a sensor employing a gel formed from an interpenetrating polymer network of poly(vinyl alcohol) and a copolymer of N-isopropylacrylamide and acrylic acid. This gel exhibits a continuous volume-phase transition that is strongly dependent on the presence of polyvalent metal ions in the gel solvent. A sensor apparatus has been constructed that estimates, in real time, the transition temperature of a gel. When this sensor is loaded with a gel sensitive to metal ions, it could be used to detect the presence and identity of metal ions in a solution.

Journal of Intelligent Material Systems and Structures, Vol. 8, No. 2, 184-190 (1997)
DOI: 10.1177/1045389X9700800209


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